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Lead, indium and tin complexes of Schiff bases derived from salicylaldehydes

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posted on 10.10.2017, 09:22 by Andrew T. Ross
A number of lead(II) complexes prepared from the reactions of various disalicylaldimines with lead(II) salts have been characterised spectroscopically, and in two cases have been analysed by X-ray diffraction. The reaction of N,N'-bis(salicylidene)ethane-1,2-diamine (H2salen) with Pb(ClO4)2·6H2O produced a novel complex [Pb3(salen)2][ClO4]2 in which the ligand bonds to the lead in two different modes. The interaction of N,N'-bis(3-methoxy-salicylidene)ethane-1,2-diamine with Pb(ClO4)2·6H2O yielded a mononuclear complex wherein the ligand bonds to the lead(II) atoms only through its phenolic oxygens. [Continues.]

Funding

EPSRC.

History

School

  • Science

Department

  • Chemistry

Publisher

© Andrew Ross

Publisher statement

This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 2.5 Generic (CC BY-NC-ND 2.5) licence. Full details of this licence are available at: http://creativecommons.org/licenses/by-nc-nd/2.5/

Publication date

1998

Notes

A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.

Language

en

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