Thesis-1998-Foreman.pdf (4.09 MB)
Download fileOrgano-sulfur phosphorus chemistry
thesis
posted on 2018-01-04, 16:32 authored by Mark R. StJ. ForemanP-organo-substituted dithiadiphosphetane disulfides have been prepared by the reaction
of ferrocene and arenes with P4S10. Reaction of these compounds and Lawesson's
reagent with alkenes, 2,3-dimethylbutadiene and other compounds gave organo-sulfur
phosphorus compounds including 1,2-thiaphosphetane-2-sulfides such as P-ferrocenyl
1,2,5,5,7,8-hexamethyltricyclo[3,2,5,2,0]-3-thia-4-phospho-oct-7-ene-4-sulfide and a
thiaphosphorine sulfide (P-ferrocenyl 4,5-dimethyl-3H,6H-1,2-thiaphosphinine-2-sulfide).
Treatment of P-ferrocenyl thiaphosphorine sulfide with BuLi followed by carbon containing
electrophiles (such as benzyl bromide or 2,4-dinitrochlorobenzene) gave ring-opened
products. In addition treatment of dithiadiphosphetane disulfides with organic carbonyl
compounds, including ketones, gave thiocarbonyl compounds. Platinum complexes were
formed from the dithiadiphosphetane disulfides. [Continues.]
History
School
- Science
Department
- Chemistry
Publisher
© Mark R. StJ. ForemanPublisher statement
This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 2.5 Generic (CC BY-NC-ND 2.5) licence. Full details of this licence are available at: http://creativecommons.org/licenses/by-nc-nd/2.5/Publication date
1998Notes
A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.Language
- en