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Preliminary studies of the reactions of alkenyl α-nitroalkyl free radicals

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posted on 2017-10-17, 10:32 authored by David Crosby
The mechanistic fate of alkenyl α-nitroalkyl free radicals generated in the following reactions has been studied: SRN1 reactions between α-bromonitro compounds and nucleophiles, reductive reactions between α-substituted nitro compounds and tri-n-butyltin(IV)hydride (Bu3SnH) or 1,4-dihydro-N-benzylnicotinamide (BNAH), oxidative reactions between alkenyl nitronate anions and nucleophiles and the photolytic rearrangement of α-iodonitro compounds have all been studied. [Continues.]

Funding

S.E.R.C. (Research Assistantship).

History

School

  • Science

Department

  • Chemistry

Publisher

© David Crosby

Publisher statement

This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 2.5 Generic (CC BY-NC-ND 2.5) licence. Full details of this licence are available at: http://creativecommons.org/licenses/by-nc-nd/2.5/

Publication date

1993

Notes

A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.

Language

  • en

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    Chemistry Theses

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    Keywords

    untaggedChemical Sciences not elsewhere classified

    Licence

    CC BY-NC-ND 2.5

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