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Some aspects of the chemistry of resorcinarenes

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posted on 04.09.2018 by Yohan Chan
This thesis has been divided in three sections. The first chapter contains a review of resorcinarene chemistry. The second chapter contains the results and the discussion and the experimental details are provided in the third chapter. The first part of chapter two contains the results and discussion related to the synthesis of benzoxazines derived from resorcin[6]arene and resorcin[4]arene and the diastereoselectivity observed in the syntheses. The second part of chapter two describes the synthesis of inherently chiral resorcinarenes using non-chiral 3-alkyloxyphenols, the synthesis of benzoxazines derived from these inherently chiral resorcinarenes and the synthesis of a pair of diastereoisomers using the 3-alkyloxyphenol derived from (R)-mandelic acid. The synthesis of a range of alkoxyesters using dimsyllithium in high yielding reactions is also discussed. [Continues.]

History

School

  • Science

Department

  • Chemistry

Publisher

© Yohan Chan

Publisher statement

This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/

Publication date

2006

Notes

A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.

Language

en

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