Thesis-1975-Sharma.pdf (2.41 MB)
Download file

Some studies in the chemistry of reactive intermediates

Download (2.41 MB)
thesis
posted on 17.09.2018, 11:34 by Ram P. Sharma
A number of reactions of tetrahalogenobenzynes have been investigated. The reactions of tetrafluorobenzyne with 2-methyl- and 2,5-dimethylfuran gave the expected Diels–Alder adducts (dihydro-tetrafluoroepoxinaphthalene derivatives) which on treatment with butadiene afforded 9-methyl- and 9,10-dimethyltetrahydrotetrafluoroanthracenes. Further reactions with tetrafluorobenzyne followed by dehydrogenation gave 9-methyl- and 9,10-dimethyloctafluorotriptycenes which were used to study new examples of long-range 19F–1H spin–spin coupling 1H NMR spectroscopy. [Continues.]

History

School

  • Science

Department

  • Chemistry

Publisher

© Ram Prakash Sharma

Publisher statement

This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/

Publication date

1975

Notes

A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.

Language

en

Usage metrics

Keywords

Exports