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Some studies in the chemistry of reactive intermediates

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thesis
posted on 06.08.2018, 14:23 by John M. Sketchley
The reactions of tetrafluorobenzyne and tetrachlorobenzyne with styrene have been investigated and found to give predominantly or exclusively 1,2,3,4-tetrahalogeno-9,10-dihydrophenanthrenes or 1,2,3,4-tetrahalogenophenanthrenes in good yield. Similar reactions are reported in which the arynes were generated in the presence of α-methyl-, trans-β-methyl-, 2-methyl-, 3-methyl-, 4-methyl-, and 2,4-dimethylstyrene. Reactions were also carried out with trans-stilbene, 1,1-diphenylethylene, 1-phenylcyclohexene and 1-vinylnaphthalene. [Continues.]

Funding

Science Research Council (research studentship).

History

School

  • Science

Department

  • Chemistry

Publisher

© John M. Sketchley

Publisher statement

This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/

Publication date

1970

Notes

A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.

Language

en

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