Thesis-1996-Keyte.pdf (3.68 MB)
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Studies of dithioimidodiphosphinates and related compounds

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thesis
posted on 13.03.2018, 10:09 authored by Robin W. Keyte
The condensation reaction of iPr2PCl with hexamethyldisilazane, HN(SiMe3)2, followed by oxidation with sulfur yields iPr2P(S)NHP(S)iPr2. Single crystal X-ray diffraction studies indicate it adopts a unique cisoid conformation in a hydrogen bonded chain. iPr2P(S)NHP(S)iPr2 was reacted with carbonates of Zn, Cd and Ni, CoCl2, MCl2COD (M = Pd, Pt) and Pt(PMe3)2Cl2 yielding the complexes M[iPr2P(S)NP(S)iPr2]2 (M = Zn, Cd, Ni, Co, Pd, Pt), {[iPr2P(S)NP(S)iPr2] Pd[iPr2P(S)NHP(S)iPr2]}+Cl- and {Pt(PMe3)2[iPr2P(S)NP(S)iPr2]}+BPh4-. [Continues].

Funding

EPSRC. Zeneca Specialties.

History

School

  • Science

Department

  • Chemistry

Publisher

© R.W. Keyte

Publisher statement

This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/

Publication date

1996

Notes

A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.

Language

en

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