Thesis-1996-Keyte.pdf (3.68 MB)
Download fileStudies of dithioimidodiphosphinates and related compounds
thesis
posted on 2018-03-13, 10:09 authored by Robin W. KeyteThe condensation reaction of iPr2PCl with hexamethyldisilazane, HN(SiMe3)2,
followed by oxidation with sulfur yields iPr2P(S)NHP(S)iPr2. Single crystal X-ray
diffraction studies indicate it adopts a unique cisoid conformation in a hydrogen
bonded chain. iPr2P(S)NHP(S)iPr2 was reacted with carbonates of Zn, Cd and Ni,
CoCl2, MCl2COD (M = Pd, Pt) and Pt(PMe3)2Cl2 yielding the complexes
M[iPr2P(S)NP(S)iPr2]2 (M = Zn, Cd, Ni, Co, Pd, Pt), {[iPr2P(S)NP(S)iPr2]
Pd[iPr2P(S)NHP(S)iPr2]}+Cl- and {Pt(PMe3)2[iPr2P(S)NP(S)iPr2]}+BPh4-. [Continues].
Funding
EPSRC. Zeneca Specialties.
History
School
- Science
Department
- Chemistry