Thesis-1970-Peake.pdf (7.83 MB)
Studies on fluorophosphoranes and phosphorus–suplhur compounds
thesisposted on 2018-08-16, 11:10 authored by Stephen C. Peake
Fluorophosphoranes are reviewed with special emphasis on compounds substituted by heteroatom-containing organic groups. Interaction of Lewis acid fluorophosphoranes with Si–M-bonded Lewis bases (where M = O, S, N) have been shown to result in fission of the Si–M bond with subsequent formation of a Si–F-bonded species on all the cases investigated. The phosphorus-containing products of such reactions are generally heteroatom-substituted fluorophosphoranes. [Continues.]
Publisher© Stephen Charles Peake
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NotesA Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.