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Tandem reactions of oxiranylcarbinyl radicals

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thesis
posted on 27.10.2017 by John A. Rudderham
The work described in this thesis is an investigation into the reactivity and possible synthetic applications of oxiranylcarbinyl radicals. These radicals rapidly rearrange via β-cleavage, which can proceed by breakage of either the C-O or the C-C bond. Cleavage of the latter only occurs when the molecule has a vinyl or phenyl stabilising group attached to the epoxide ring. [Continues.]

Funding

EPSRC. SmithKline Beecham Pharmaceuticals.

History

School

  • Science

Department

  • Chemistry

Publisher

© John Andrew Rudderham

Publisher statement

This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 2.5 Generic (CC BY-NC-ND 2.5) licence. Full details of this licence are available at: http://creativecommons.org/licenses/by-nc-nd/2.5/

Publication date

1997

Notes

A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.

Language

en

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