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The analytical chemistry of o,o'-dihydroxydiphenyl sulphides and methanes

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posted on 09.07.2018, 14:18 by A. Gray
The formation of a number of metal complexes of the o,o'-dihydroxydiphenyl methane and sulphides, hexachlorophene, bithionol end fenticlor have been investigated, and their stability constants determined in 3+1 v-v ethanol–water solution at ionic strength one. The proton-ligand stability constants of dichlorophene, bromchlorophene and tetrachlorophene have also been determined under these conditions. A solvent extraction procedure has been developed for the calorimetric determination of iron(III) with bithionol as reagent. The use of bithionol as a gravimetric reagent for mercury(II) has been investigated, but the reproducibility of recoveries obtained for similar samples was generally poor. [Continues.]

Funding

Science Research Council.

History

School

  • Science

Department

  • Chemistry

Publisher statement

This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/

Publication date

1970

Notes

A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.

Language

en

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