posted on 2018-10-25, 10:29authored byTrevor G. Clarke
Methods for the oxidation of aralkyl compounds have been examined
with special reference to the oxidation of toluene and O-toluenesulphonamide.
Catalytic aerial oxidations have been investigated as
possible procedures with an industrial application. The stability
of O-toluenesulphonamide towards oxidation is accounted for and the
mechanism of oxidation of toluene by both homolytic and heterolytic
bond fission is discussed. The preparation of saccharin by oxidation
of O-toluenesulphonamide with manganese dioxide in acid solution is
reported. [Continues.]
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Publication date
1968
Notes
A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.